chemistry.foundation
Terms

Glossary

The vocabulary of chemistry, in plain words.

Atom
The smallest unit of an element: a nucleus of protons and neutrons surrounded by electrons.
Element
A substance whose atoms all have the same number of protons.
Isotope
Atoms of one element that differ in their number of neutrons.
Ion
An atom or molecule carrying a net electric charge.
Molecule
Two or more atoms held together by covalent bonds.
Compound
A substance made of two or more elements in fixed proportion.
Mole
The SI unit of amount of substance: exactly 6.02214076 × 10²³ entities.
Stoichiometry
The arithmetic of reactions — how much of each reactant and product.
Valence
The number of bonds an atom typically forms.
Electronegativity
How strongly an atom attracts the electrons in a bond; Pauling’s scale is the usual measure.
Oxidation state
The charge an atom would have if all its bonds were fully ionic. Book-keeping, but useful.
Redox
Reduction and oxidation: reactions in which electrons pass from one species to another.
Acid and base
In the Brønsted–Lowry sense (1923), an acid gives up a proton and a base accepts one.
pH
The negative logarithm of hydrogen-ion activity; introduced by Søren Sørensen in 1909.
Catalyst
A substance that speeds a reaction without being consumed by it.
Enthalpy
Heat content at constant pressure.
Entropy
A measure of how many microscopic arrangements match a given state.
Gibbs free energy
Enthalpy minus temperature times entropy; its sign tells which way a reaction can go.
Equilibrium constant
The ratio of products to reactants once a reaction has stopped changing.
Isomer
Compounds with the same formula but different structures.
Chirality
The property of a molecule that cannot be superimposed on its mirror image.
Functional group
A cluster of atoms that reacts in a characteristic way wherever it appears.
Polymer
A large molecule built from many repeated units.